Interesting comment from You mictester? LOL
""Unless you want to indulge in "trial and (t)error" you'll have to do some mathematics!""
My thought,, Yes But even if one spends time to learn the maths one still won't know how the maths will sound when finished?
So for those with limited experience you are left between a rock and a hard place,, ouch!
A few words from my experience with audio stuff may help some,,Or put in real terms,,How a poor man can learn to come to grips with circuits.
And BTW I've done all this on a shoe string budget.
Go buy a bread board kit and throw in some parts and add a plug pak and like stuff. Now D/load some sims and work between the two.
Next;
Wire up the circuit you wish to play with then STOP. Now go simulate the same thing. Use the *Bode plotting or AC analysis* screen so you can observe how the circuit reacts to different settings of the Tone controls.
Now you have a system which allows you to not only SEE the difference but you can also HEAR the result.

Now it's just a matter of swapping a few R's And C's to find the magic.
I've not yet been able to find a faster more accurate way to study a circuit in a relatively short time frame for the cost outlay. Winky.
Bear in mind I Failed at maths and never finished skool.

So if I can do it So can you
For me I'm far to old to go back and learn all that is needed to be a competent technical person but I wanted to learn to understand why certain things worked and other systems don't fair so well.
The above setup has allowed me to learn what would have taken me years of struggle. Here is a screen shot of my not so famous tone circuit which I believe is far superior over most of the more popular Tone systems for guitar Amps.
FWIW,,My observations of tone systems for guitar, in general;
If you want to boost X freq then boost big round curves, not peaks. (inverted scoops, see my PhAbbTone Plot as example)
Now if you want to cut, then use deep narrow notching circuits. Some parametrics work well but most folks don't understand how to use them correctly. (Parametric systems tend to work far better in Cut mode NOT boost mode. Hint)
Sadly the mindset of the average player is Primed by human nature and add some BS advertizing that MORE is always better than less when in fact the opposite will likely attain far better results.
For Tone systems to be Convincing you need to pull the frequency *You don't want* OUT.
Shallow scoops rob the energy from your signal and often become dead pan and are nowhere near as convincing as deep narrow cuts.
Baxandall tone circuits tend to work on boost which is fine but I've had far better success with the Dave Reeves (HiWatt) inspired mid cut ability of my PhAbbTone circuit. Stuck in front of a stock Fender Dudville 212 will open your eyes and drop a jaw or two
It will then actually sound like a ,,,, well a fender amp.
I'm adding my contour filter circuit to show how to add even more tonal extremes. This filter takes over where your other tone circuit ( whatever you use) leaves off.
This is capable of deep narrow -20Db notching which is sweepable from about 600Hz < 2,500Hz.
Metal freaks take note; The term often used to describe metal tone is *Mid scooped tone*. Trust me you will have far better success with a *deep narrow notch*. If you are chasing those tones then add My contour/notch filter *After* your dirt boxes.
For me I'm loving the extreme tonal abilities of these two systems when used together,
The PhAbbTone and the Contour filter. winky.
@ pedalgrinder;
Far too busy at the moment to sim or test the idea shown but it should now be obvious that *IF* it can produce a deep notch then I'd say you are onto something good.
Final words;
The greatest guitar sounds are so because of what you *Can't Hear*
For tone controls to work you have to take something away,, not add.
Hope it helps someone sort through the maze of confusion. Have fun, Phil.

- PhAbbTone Response curves

- Sweepable notch cut filter